@article{oai:tobunken.repo.nii.ac.jp:00003693,
 author = {加藤, 将彦 and 丹沢, 穣 and 平井, 昭司 and 早川, 泰弘 and 三浦, 定俊 and Masahiko, KATO and Yutaka, TANZAWA and Shoji, HIRAI and \nYasuhiro, HAYAKAWA and Sadatoshi, MIURA},
 issue = {46},
 journal = {保存科学, Science for conservation},
 month = {Mar},
 note = {“Kaishunsai Paints” are painting materials collected and stored by the Nabeshima family in Takeo city, Saga prefecture during the Edo period. Approximately 200 samples were obtained and analyzed non-destructively. In this report, the results of elemental analysis by X-ray fluorescence spectrometry, identification of chemical compounds by X-ray diffraction analysis, observation of particles by digital microscope and quantification of color by spectral photometer are presented.
 The identified materials in these analyses are as follows:
(1) White-colored samples
 Chalk (CaCO3), white mica (KAl2(Si3Al)O10(OH,F)2) and cerussite (PbCO3)
(2) Red-colored samples
 Cinnabar (HgS), red iron oxide (Fe2O3), red lead (Pb3O4) and others
(3) Yellow-colored samples
 Cobalt glass, SiO2 and others
(4) Green-colored samples
 Malachite (Cu2(CO3)(OH)2) and a material containing Mn as a major component
(5) Blue-colored samples
 Azurite (Cu3(CO3)2(OH)2), smalt, ultramarine blue (Na2Al6Si6O24S) and prussian blue (Fe4[Fe(CN)6]3)
(6) Black-colored samples
 Magnetite (Fe3O4) and CuO
(7) Metal samples
 Gold (Au), sliver (Ag) and brass powder (Cu-Zn)

 New findings were obtained especially for the green-colored samples. Philipsburgite ((Cu,Zn)6(AsO4,PO4)2(OH)6･H2O), adamite ((Zn,Cu)2(AsO4)(OH)), and rosasite (CuZn(CO3)(OH)2) were identified as compounds that contain Cu, Zn and As coexisting with malachite (Cu2(CO3)(OH)2). 
 These data are expected to be used as basic data for pigments analysis.},
 pages = {61--74},
 title = {〔報文〕武雄鍋島家所蔵皆春齋絵具の材質分析},
 year = {2007}
}